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Showing posts with the label Photochemistry

Sunlight Cloud Chemistry Atmospheric Oxidants

Sunlight in Clouds Creates Hidden Oxidants, Scientists Reveal Atmospheric Chemistry Breakthrough with Global Implications Hydroperoxides are powerful oxidizing agents that play a crucial role in atmospheric chemistry. An international research team, including scientists from the Leibniz Institute for Tropospheric Research (TROPOS), has now revealed that these compounds can also form from  α -keto acids such as pyruvic acid in clouds, rain and aerosol water when exposed to sunlight . The researchers estimate that these reactions could account for between 5 and 15% of hydrogen peroxide ( H₂O₂ ) observed in the atmosphere's aqueous phase. Published in Science Advances , the findings identify the photolysis of  α -keto acids  as a previously unrecognized source of atmospheric oxidants. Because such oxidation processes affect both the formation and breakdown of airborne particles and pollutants, the discovery has important implications for air-quality and climate modellin...